Temperature dependence of the derived properties of mixtures containing chlorobenzene and aliphatic linear alkanes (C6–C12)

gpch20_v051_i03_coverPCL-48-5-2010-661-681

This  article  reports  experimental densities, refractive indices and speeds of  sound  of  the  binary  mixtures  chlorobenzene + (n-hexane,  n-heptane, n-octane,   n-nonane,   n-decane,   n-undecane   or  n-dodecane)   and  speeds of sound  of the ternary
mixtures  chlorobenzene + n-hexane + (n-undecane or  n-dodecane)   at  298.15
K  and  atmospheric   pressure,  over  the  whole concentration range. The corresponding derived properties  were computed from the experimental data.
The results were fitted by means of the Redlich–Kister equation  for binary  mixtures and the Nagata  equation  for ternary mixtures. A set of estimation methods were applied, and an interpretation in terms  of structure  and length  of molecular  chain  of the n-alkane
molecules was made

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